By Bard A.J.
The 1st resource in this increasing analytical technological know-how, this reference explores advances within the instrumentation, layout, and alertness of ideas with electrogenerated chemiluminescence (ECL), studying the use and impression of ECL-based assays in scientific diagnostics, lifestyles technological know-how examine, environmental trying out, nutrients and water review, and the detection of biowarfare brokers. Compiled by means of the pioneer of this hugely leading edge know-how, this quantity offers contributions from sixteen prime gurus. They talk about the simulation of ECL habit utilizing advertisement software program, summarize key features of natural ECL platforms, and canopy advancements in steel chelate ECL.
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Additional info for Electrogenerated Chemiluminescence (Monographs in Electroanalytical Chemistry and Electrochemistry Series)
Am. Chem. Soc. 1966, 88, 390; J. Phys. Chem. 1966, 70, 3928. 32. J. J. Am. Chem. Soc. 1971, 93, 5959. 33. J. J. Am. Chem. Soc. 1971, 93, 5968. 34. M. Anal. Chem. 1993, 65, 2576. 35. W. J. Am. Chem. Soc. 1959, 81, 5001. 36. A. Acc. Chem. Res. 1975, 8, 231. 37. M. J. Am. Chem. Soc. 1966, 88, 4745. 38. J. J. Am. Chem. Soc. 1972, 94, 2862. 39. Chang, M. Saji, T. J. J. Am. Chem. Soc. 1977, 99 5399. 40. Rubinstein, I. J. J. Am. Chem. Soc. 1981, 103, 512. 41. D. Anal. Chem. 1987, 59, 865. 42. J. J. Electrochem.
However, with such systems, triplets can be formed in ECL by adjustment of the energetics of the annihilation reaction, where TTA is then observed. Thus states are sometimes accessible in ECL that are not available spectroscopically. C. , D* + Q → D + Q* (27) where Q* can often decay to the ground state without emission. Quenching can occur by either energy transfer or electron transfer. Energy transfer, sometimes called Förster transfer, is favored by the electronic energy of D* being greater than that of Q* and a large overlap of the emission band of D* with the absorption band of Q.
Soc. 1964, 86, 5350. 26. J. J. Am. Chem. Soc. 1965, 87 139. 27. M. US Patent 3,654,525, April 4, 1972. 28. E. US Patent 3,319,132, May 9, 1967. 29. J. J. Am. Chem. Soc. 1969, 91, 209. 30. A. J. Chem. Phys. 1965, 43, 2654. 31. W. J. Am. Chem. Soc. 1966, 88, 390; J. Phys. Chem. 1966, 70, 3928. 32. J. J. Am. Chem. Soc. 1971, 93, 5959. 33. J. J. Am. Chem. Soc. 1971, 93, 5968. 34. M. Anal. Chem. 1993, 65, 2576. 35. W. J. Am. Chem. Soc. 1959, 81, 5001. 36. A. Acc. Chem. Res. 1975, 8, 231. 37. M. J. Am.