By Mara G. Freire
This ebook bargains complete details at the basics and functions of ionic-liquid-based aqueous biphasic platforms, that have predominantly (and effectively) been hired as replacement systems for the extraction, separation and purification of various high-value items. The e-book comprises an preliminary advent supplying a quick evaluation, from basics to purposes, through 9 chapters addressing the respective section diagrams (interpretation and characterization) and memorable examples in their functions. it is also ultimate chapters concentrating on fresh advancements within the look for extra environmentally-benign and biocompatible ionic-liquid-based aqueous biphasic structures, and at the growth made to this point about the restoration, recycling and reuse of the phase-forming elements, the aim being the improvement of low-cost and sustainable methods. The e-book bargains an engaging and helpful advisor for a vast readership within the fields of eco-friendly chemistry, biotechnology, chemical engineering, and biochemistry, between others.
Mara G. Freire is a Coordinator Researcher at CICECO - Aveiro Institute of fabrics, Chemistry division, college of Aveiro, Portugal.
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Extra info for Ionic-Liquid-Based Aqueous Biphasic Systems: Fundamentals and Applications
Freire MG, Neves CMSS, Marrucho IM, Canongia Lopes JN, Rebelo LPN, Coutinho JAP (2010) High-performance extraction of alkaloids using aqueous two-phase systems with ionic liquids. Green Chem 12:1715–1718 82. Passos H, Trindade MP, Vaz TSM, da Costa LP, Freire MG, Coutinho JAP (2013) The impact of self-aggregation on the extraction of biomolecules in ionic-liquid-based aqueous two-phase systems. Sep Purif Technol 108:174–180 83. Pereira JFB, Ventura SPM, e Silva FA, Shahriari S, Freire MG, Coutinho JAP (2013) Aqueous biphasic systems composed of ionic liquids and polymers: a platform for the purification of biomolecules.
Da Costa Lopes and R. Bogel-Łukasik Polysaccharides H OH O H H H OH H H H O O H H O H OH H O O OH OH H H H n H OH H OH H H H OH OH H O n O H H OH H H OH H OH H H OH OH H H H O H O H OH OH n amylose O H OH OH H H O H OH H H O OH H H O O O OH H OH OH OH OH OH OH H OH OH H H OH H O O H n OH OH H O O OH cellulose OH OH H OH agarose H OH H H O OH H OH H O OH n amylopectine starch - composed of amylose to amylopectin in the relative ratio oscillating around 20:80 OH OH H H O H O H NHCOCH3 H OH O O OH H O H OH H CH2 n H O H chitosan OH H OH OH chitin OH O H NH2 H n H H O H O O H H O HO NH2 H O H H OH H H OH NHCOCH3 H O H OH O H COOCH3 OH O OH H H H O OH O pectin O H H COOCH3 OH H H H O H OH OH H OH H H O n O H H H OH xylan OH H OH OH O H H OH H O OH CH2 OH H H H OH OH n H H OH OH H O H OH H O OH n inulin Fig.
However, and even if more benign ABS phase-forming components are used, it is critical to develop effective approaches for their recovery and reuse, both to decrease the overall environmental footprint and to decrease the associated costs of the foreseen large-scale and sustainable ABS-related technologies. In the past few years, authors started looking into the recovery of the target compounds, followed by the recovery and recycling of ILs [66, 75, 84, 91–93]. This trend is not surprising given current sustainability concerns and moderately high cost of ILs.